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polymerization of propylene catalyzed by TiCl 3 + (BCH3hAII the stereochemistry of the very first insertion is the same as that of subsequent units despite the lack of asymmetry in the original alkyl group of the activator. 2. Occasional defects in the polymer chain remain isolated. When propylene reacts from the opposite prochiral face bringing about a syndiotactic error (Scheme 13.7, a), the original chirality center preceding the error continues to be formed. The same is true for a secondary defect or type 2-1 insertion (Scheme 13.7, b) which is a head-to-head addition and creates a CH 2-CH 2 sequence. If the chirality were controlled by the growing chain end, an error would be perpetuated, giving rise to a polymer block with altered chirality. Instead, isotacticity is maintained in both cases.

a, b [ Z ; r0 a; r1 b r0 c1r1 r2 r1 c2r2 r3 r2 c3r3 r4 . . . 0 , r2 , r1 0 , r3 , r2 0 , r4 , r3 . . . r2 r0 (modulo r1) r3 r1 (modulo r2) r4 r2 (modulo r3) . . .

This next example shows how to revolve a MovieClip object (on the main timeline) around a circular path. First, to make it easier, you want to adjust the _x and _y properties of the main movie clip, as well as set up a few properties of the revolving object mcBall.

Because the key is specified as a string when using array-access notation, you can use key names that you cannot use in dot syntax. For example, you cannot do the following:

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For comma-separated value (CSV) files, the process is slightly more complicated because a value in a CSV file is normally additionally qualified with double quotes to ensure that any data that may include a comma is not misunderstood during parsing. Although you could develop such a solution yourself, it s easier to use an existing module. In this case, I use the Text::CSV_XS module to do the parsing. Listing 5-2 shows an example of an application in action.

Optical methods for ow measurement and mixing system validation, Proc 15th Polymer Society International Meeting, Hertogenbosch, The Netherlands Irving, H F, and R L Saxton (1967) Mixing of high viscosity materials, in Mixing: Theory and Practice, Vol II, V W Uhl and J B Gray, eds, Academic Press, New York Jaffer, S A, V L Bravo, P E Wood, A N Hrymak, and J D Wright (2000) Experimental validation of numerical simulations of the kneading disc section in a twin screw extruder, Polym Eng Sci, 40(4), 892..

In a commercial or production environment, the constraints of deadlines often preclude creating documents completely from scratch. Besides, there s no need to keep reinventing the wheel. Often, things such as icons and buttons can be quickly based on existing clip art images, which are easily modified in Fireworks to suit a particular project. Fireworks includes an extensive collection of clip art on its CD-ROM; almost 2,000 separate Fireworks documents. Thankfully, these documents are also referenced by an Extensis Portfolio database file called Fireworks MX Clipart.fdb. This document opens in the free Extensis Portfolio browser also included on the CD-ROM displaying thumbnails for each and every clip art document. Use the Portfolio Browser to search or browse for a particular document. Double-click a thumbnail in order to view it at full size; right-click (Control-click) a thumbnail, and choose Edit Original from the context menu in order to open it in Fireworks for editing. After you open the thumbnail in Fireworks, you can drag and drop elements into other Fireworks documents.

There are approximately 2 107 naturally occurring organic compounds in the biosphere globally and ~100,000 distinct natural products in a given freshwater sediment sample (Seffernick and Wackett, 2001; Wackett and Hershberger, 2001). Furthermore, several million organic compounds have been synthesized by organic chemists (Seffernick and Wackett, 2001). Many synthetic compounds have novel molecular structures [e.g., polymeric plastics and halogenated pesticides like DDT (dichloro-diphenyl trichloroethane)], though the uniqueness of synthetic ( xenobiotic ) compounds is not easy to discern, given the immense and unknown diversity of naturally occurring compounds. Current dogma in the biodegradation literature is that all naturally occurring organic compounds are biodegradable . A corollary of this is that truly novel molecular structures should not be biodegradable because there is no evolutionary precedent, no selective pressure, for their metabolism . After all, genetic mutation involves alteration of an existing DNA

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